The first catalytic asymmetric hetero-Diels-Alder (HDA) reaction between 3-tert-butyldimethylsilyloxy-1-dimethylamino-1,3-pentadiene (4-methyl-substituted Rawal's diene) and aldehydes is described. With 3 mol % of dirhodium(II) tetrakis[N-benzene-...
Organic and Biomolecular Chemistry 11(32) 5374-5382 2013年8月 [査読有り]
The first catalytic asymmetric carbonyl ylide cycloaddition with arylallenes is described. With dirhodium(ii) tetrakis[N-tetrachlorophthaloyl-(S) -tert-leucinate], Rh2(S-TCPTTL)4, the cycloaddition of carbonyl ylides derived from diazoketoesters w...
The first example of dirhodium(II) complex-catalyzed asymmetric intermolecular C-H insertion with α-alkyl-α-diazoesters is described. The reaction of 1,4-cyclohexadiene with 2,4-dimethyl-3-pentyl α-alkyl-α-diazoacetates under catalysis by dirhodiu...
The immobilization of dirhodium(II) tetrakis[N-tetrafluorophthaloyl-(S)-tert-leucinate], [Rh-2(S-TFPTTL)(4)], has been accomplished by co-polymerization of a dirhodium(II) complex-containing monomer with styrene and 1,6-bis(4-vinylbenzyloxy) hexan...
CHEMICAL COMMUNICATIONS 48(55) 6969-6971 2012年 [査読有り][招待有り]
The first catalytic asymmetric hetero-Diels-Alder reaction between 2-aza-3-silyloxy-1,3-butadienes and aldehydes is described. With dirhodium(II) tetrakis[N-benzene-fused-phthaloyl-(S)-piperidinonate], Rh-2(S-BPTPI)(4), the cycloaddition reaction ...