This study demonstrates a novel method for synthesizing rare heterocyclic compounds, namely, cyclic isoureas using alkenoic ureas via cobalt-catalyzed metal-catalyzed hydrogen atom transfer/radical polar crossover (MHAT/RPC). This method successfu...
In this study, we investigated the metal-catalyzed hydrogen atom transfer (MHAT)/radical polar crossover (RPC) reaction, focusing on the influence of ligands on the cyclization selectivity by employing substrates containing two nucleophiles along ...