The palladium-mediated intramolecular biarylation of the cyclic triamide of 2-bromo-4-(isobutylamino)benzoic acid proceeded effectively by the introduction of three methyl groups and the use of tri-tert-butylphosphine as the ligand.
Chemical & pharmaceutical bulletin 70(2) 187-191 2022年 [査読有り]
A new pentacyclic monoterpenoid indole alkaloid glycoside named secorubenine (1) was isolated from the heartwood of Adina rubescens, collected in Indonesia. The structure was elucidated by spectroscopic analysis and chemical modification of isolat...