The immobilization of functional units in the interlayer spaces of layered silicates and titanates is summarized from the viewpoint of how the spatial distribution of functional units in the interlayer affects the performance of the intercalation ...
A water soluble polymer, poly(vinyl pyrrolidone) (PVP), was intercalated into the two dimensional interlayer space of a layered silicate, synthetic saponite (Sumecton SA; Kunimine Ind. Co.), which adsorbed rhodamine 6G (R6G) by ion exchange. The b...
Microporous and Mesoporous Materials 142(1) 363-370 2011年6月
The adsorption of tris(2,2′-bipyridine)ruthenium(II) ([Ru(bpy) 3 ] 2+ ) onto aluminum containing mesoporous silicas (BJH pore size of 2.2 and 3.0 nm and Si/Al ratio of ca. 26) was conducted and the photoluminescence of the products was examined as...
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 84(6) 617-619 2011年6月
The excited state relaxation of tris(2,2'-bipyridine)ruthenium(II) ([Ru(bpy)(3)](2+)) in aluminum containing mesoporous silica was investigated as a function of loading amount and temperature. The concentration dependence of [Ru(bpy)(3)](2+) on th...
Synthetic saponites containing photosensitizing dyes (1,1'-diethyl-2,2'-cyanine (pseudoisocyanine) or tris(2,2'-bipyridine)ruthenium(II)) in the interlayer space were complexed with nanocrystalline anatase. The photostability of the...