草部 浩一

<jats:p>Photoinduced phase transition (PIPT) involves substantial changes in both electronic and crystallographic structures caused by electron excitations. Because PIPT is ultrafast and exhibits inhomogeneous behavior, its fundamental processes, in particular, how the ultrafast dynamics of photoexcited electrons trigger lattice deformation and the timescales involved, remain poorly understood. In this study, phase transition and its spatial separation in organic charge-transfer complexes was investigated using photoemission electron microscopy with femtosecond pulsed laser excitation. First, the thermally induced phase transition was confirmed by imaging the morphology change and also by observing the change of spectral shape around the Fermi level. Second, the escape time of photoexcited electrons or the heat generated by the laser pulses is estimated by observing the morphology change depending on the laser repetition rate. Finally, the dynamics of the photoexcited electrons and the subsequent morphology change are directly visualized. The results show that an anisotropic morphology change is initiated following the accumulation of electrons in unoccupied states over approximately a picosecond.</jats:p>