Chemistry - A European Journal 24(32) 8228-8232 2018年6月 [査読有り]
The preparation of homo- and heterocomplexes composed of the parent perylene diimide (PH) and pyrrolidine-substituted perylene diimide (PN) in DNA and rapid electron transfer in these complexes, which has been analyzed by steady-state fluorescence...
Abstract In this report, we describe the circularly polarized luminescence (CPL) of the RNA duplexes having one to four 2′‐O‐pyrene modified uridines (Upy) and the DNA duplexes having two, four, and six pyrene modified non‐nucleosidic linkers (Py)...
The construction of one-dimensional chromophore aggregates of naphthalenediimide (NDI) and bis(2-thienyl)diketopyrrolopyrrole (TDPP) using 40-mer oligodeoxythymidines (dT40) as a scaffold was previously reported. Furthermore, the chromophore-aggre...
Chemistry - A European Journal 23(72) 18258-18263 2017年12月 [査読有り]
This work describes the formation of a porphyrin (Por) dimer using a DNA duplex as a scaffold and photocurrent generation from electrodes modified with a monolayer of Por–DNA conjugates. The solid-phase click reaction between an azide-porphyrin an...
We describe the synthesis, binding, and electrochemical properties of ferrocene-conjugated oligonucleotides (Fc-oligos). The key step for the preparation of Fc-oligos contains the coupling of vinylferrocene to 5-iododeoxyuridine via Heck reaction....
Upon UV-irradiation of alken-1-yl aryl methyl phosphates in methanol a cationic migration of an aryl group to a neighbouring olefinic moiety to produce arylalkanone and arylalken-1-yl methyl ether has been observed.
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 68(11) 3189-3197 1995年11月
Upon UV irradiation in acetonitrile, tri-1-naphthyl phosphate and di-1-naphthyl methylphosphonate underwent intramolecular rearrangement and ipso-coupling to give 1,2'-binaphthalen-1'-ol and 1,1'-binaphthalene, respectively. In the photolyses of t...
M. Nakamaura, T. Takada, K. Yamana(範囲:Templated Arrays of Multichromophores and Oligonucleotides Supported by Metal Interactions and Their Functional Relevance)
大学本部
工学研究科