DNA oligomers possessing a 2-nitrobenzyl (NB) protected thiol group have been prepared. The photo-remove of the NB to generate a free thiol group in DNA has been analyzed by using reverse-phase HPLC and denaturing gel electrophoresis. The photo-tr...
CHEMISTRY-A EUROPEAN JOURNAL 18(1) 196-201 2012年1月 [査読有り]
p-Stacked naphthalenediimide (NDI) arrays are of interest as charge-transport materials. We have designed and synthesized an NDI derivative with two ZnIIcyclens that act as receptors for the thymine base in DNA. UV/Vis and CD spectroscopy, gel fil...
The binding and fluorescence properties of complementary RNA sequences attached to different numbers of pyrenes via one carbon linker at the 2'-O-positions have been investigated. Upon hybridization of the pyrene-modified RNA sequences, the modifi...
Electron transfer (ET) through RNA duplexes possessing 2'-O-pyrenylmethy uridine (Upy) and 5-bromouracil (BrU) as an electron donor and accepter set was investigated. Reductive decomposition of the BrU resulted from the ET over long distances...
We describe an approach to the development of a new electronic aptamer-based biosensor for multiprotein targets on a single platform. The multiple protein biosensing involves the co-adsorption of several thiol-terminated capture DNA sequences on a...
M Nakamura   Y Okamoto   S Takamuku   
CHEMICAL COMMUNICATIONS (2) 209-210 1996年1月
Upon UV-irradiation of alken-1-yl aryl methyl phosphates in methanol a cationic migration of an aryl group to a neighbouring olefinic moiety to produce arylalkanone and arylalken-1-yl methyl ether has been observed.
M NAKAMURA   K SAWASAKI   Y OKAMOTO   S TAKAMUKU   
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 68(11) 3189-3197 1995年11月
Upon UV irradiation in acetonitrile, tri-1-naphthyl phosphate and di-1-naphthyl methylphosphonate underwent intramolecular rearrangement and ipso-coupling to give 1,2'-binaphthalen-1'-ol and 1,1'-binaphthalene, respectively. In the photolyses of t...
M. Nakamaura, T. Takada, K. Yamana(範囲:Templated Arrays of Multichromophores and Oligonucleotides Supported by Metal Interactions and Their Functional Relevance)